Enzymatic monolithic reactors for micropollutants degradation
نویسندگان
چکیده
Silica monoliths with uniform macro-/mesoporous structures (20 μm and 20 nm macro- mesopores diameters, respectively), high porosity (83 %) surface area (370 m2 g−1) were prepared. The grafted amino groups (0.9 mmol NH2 used to immobilize laccase from Trametes versicolor by covalent grafting glutaraldehyde (GLU) (1.0 GLU leading an ABTS activity of U g−1. Immobilization yield was 80 %, based on the difference initial final enzymatic solution for immobilization. Enzymatic degradation tetracycline (TC) in aqueous mg L−1) continuous flow recycling configuration. TC efficiency found be 40–50 % after 5 h reaction at pH 7. during 75 sequential operation without losing activity. A Steady-state computational fluid dynamics (CFD) model Michaelis Menten kinetics, allowed computing efficiency.
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ژورنال
عنوان ژورنال: Catalysis Today
سال: 2021
ISSN: ['0920-5861', '1873-4308']
DOI: https://doi.org/10.1016/j.cattod.2020.04.048